Ethyl 2-(1H-1,2,3-benzotriazol-1-yl)acetate

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2-(1H-Benzotriazol-1-yl)-1-(3-methyl­benzo­yl)ethyl benzoate

In the title mol-ecule, C(23)H(19)N(3)O(3), the dihedral angles between the mean plane of the benzotriazole ring system and the benzene and phenyl rings are 9.67 (9) and 86.08 (10)°, respectively. The dihedral angle between the benzene and phenyl rings is 85.89 (11)°. In the crystal structure, weak inter-molecular C-H⋯O hydrogen bonds link mol-ecules into chains along [010].

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2-(1H-Benzotriazol-1-yl)-1-(3-methoxy­benzo­yl)ethyl isonicotinate

In the title compound, C(22)H(18)N(4)O(4), mol-ecules are linked to each other by C-H⋯N and C-H⋯O inter-molecular hydrogen-bonding inter-actions. The crystal packing is further stabilized by C-H⋯π, and π-π inter-actions with a distance of 3.783 (3) Å between the centroids of the benzene rings of the benzotriazole system.

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2-(1H-Benzotriazol-1-yl)-1-(3-bromo­benzo­yl)ethyl benzoate

In the title compound, C(22)H(16)BrN(3)O(3), the dihedral angles between the benzotriazole mean plane and the benzene rings of 4.84 (1) and 89.50 (1)°. The dihedral angle between the two benzene rings is 84.77 (1)°. In the crystal structure, mol-ecules are linked into chains by inter-molecular C-H⋯O hydrogen bonds. The crystal packing is further stabilized by C-H⋯π inter-actions.

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Ethyl 2-(1H-1,2,3-benzotriazol-1-yl)acetate

The title compound, C(10)H(11)N(3)O(2), was synthesized by the reaction of 1H-benzotriazole with ethyl 2-chloro-acetate in ethanol. The non-H atoms, excluding the benzotriazol-1-yl group, are almost coplanar (r.m.s. deviation of the non-H atoms = 0.0409 Å). The dihedral angle formed between this plane and the benzotriazole ring is 79.12 (5)° In the crystal, weak inter-molecular C-H⋯N and C-H⋯O ...

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2-(1H-Benzotriazol-1-yl)-1-(2-chloro­benzo­yl)ethyl 4-methyl­benzoate

In the mol-ecule of the title compound, C(23)H(18)ClN(3)O(3), the essentially planar benzotriazole ring makes dihedral angles of 52.93 (1) and 85.21 (1)°, respectively, with the chloro-phenyl and tolyl rings. The crystal packing is stabilized by π-π [centroid-to-centroid distance 3.830 (2) Å, interplanar distance 3.705 Å, slippage 0.968 Å]; C-H⋯π⋯tolyl ring inter-actions are also present.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s160053681005138x